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|Section2= |Section3= |Section7= |Section8= }} Vanadium(III) bromide, also known as vanadium tribromide, is VBr3. In the solid-state, this species is a polymeric with octahedral vanadium(III) surrounded by six bromide ligands. VBr3 has been prepared by treatment of VCl4 with HBr: ::2 VCl4 + 8 HBr → 2 VBr3 + 8 HCl + Br2 The reaction proceeds via the unstable vanadium(IV) bromide, VBr4, which releases Br2 at room temperature.〔Calderazzo, F.; Maichle-Mossmer, C.; Pampaloni, G. and Strähle, J., "Low-temperature Syntheses of Vanadium(III) and Molybdenum(IV) Bromides by Halide Exchange", Journal of the Chemical Society, Dalton Transactions, 1993, pages 655-8.〕 Like VCl3, VBr3 forms red-brown soluble complexes with dimethoxyethane and THF, such as mer-VBr3(THF)3.〔G. W. A. Fowles, G. W. A.; Greene, P. T.; Lester, T. E. "Ether Complexes of Tervalent Titanium and Vanadium" J. inorg, nucl. Chem., 1967. Vol. 29. pp. 2365 to 2370.〕 Aqueous solutions prepared from VBr3 contain the salt trans-()+. Evaporation of these solutions give the salt trans-()Br.〔Donovan, W. F.; Smith, P. W. "Crystal and Molecular Structures of Aquahalogenovanadium(1ii) Complexes. Part 1. X-Ray Crystal Structure of trans-Tetrakisaquadibromovanadium(III) Bromide Dihydrate and the lsomorphous Chloro-compound" Journal of the Chemical Society, Daltor Transactions." 1975, pages 894-896.〕 ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Vanadium(III) bromide」の詳細全文を読む スポンサード リンク
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